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Fatigue-free dielectric capacitor with giant energy density based on lead-free Na0.5Bi0.5TiO3-based film

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Abstract

Lead-free inorganic dielectric film capacitors have ignited plenty of interest in developing the dielectric energy storage. Here, we obtained a 0.5 mol% Ce and 2 mol% Mn-codoped 0.94Na0.5Bi0.5TiO3–0.06BaTiO3 [(Ce,Mn):NBT–BT] ceramic film capacitor on Pt/TiO2/SiO2/Si substrate, which has a significantly improved recoverable energy storage density Wrec ~ 64.2 J/cm3 and efficiency η ~ 68.1% at 2105 kV/cm. The film capacitor exhibits superior frequency stability with small gradient of 5.9% for Wrec in the frequency range of 500 Hz to 20 kHz, and excellent cycling reliability over 108 charge–discharge cycles without fatigue deterioration. Besides, the (Ce,Mn):NBT–BT film capacitor has large discharged energy density of 43.0 J/cm3 at 1579 kV/cm and fast discharging speed of 55.1 μs tested by a resistance–capacitance circuit with a load resistor of 100 kΩ. These findings indicate that the (Ce,Mn):NBT–BT film might be promising lead-free dielectrics for energy storage applications.

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Acknowledgment

This work was supported by the National Natural Science Foundation of China (No. 51972144), Shandong Provincial Natural Science Foundation of China (ZR2017LEM008) and the Key R&D Program of Shandong Province (2019GGX102015).

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Authors and Affiliations

  1. Shandong Provincial Key Laboratory of Preparation and Measurement of Building Materials, University of Jinan, Jinan, 250022, China

    Yajie Han, Jin Qian & Changhong Yang

  2. School of Materials Science and Engineering, University of Jinan, Jinan, 250022, China

    Yajie Han, Jin Qian & Changhong Yang

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  1. Yajie Han
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Correspondence to Changhong Yang.

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Han, Y., Qian, J. & Yang, C. Fatigue-free dielectric capacitor with giant energy density based on lead-free Na0.5Bi0.5TiO3-based film. J Mater Sci: Mater Electron 30, 21369–21376 (2019). https://doi.org/10.1007/s10854-019-02513-4

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