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Acrylic and Modacrylic Fibers

Acrylic A manufactured fiber in which the fiber


forming substance is any long chain synthetic polymer
composed of at least 85% by weight of acrylonitrile units
.
Modacrylic A manufactured fiber in which the fiber
forming substance is any long chain synthetic polymer
comprised of less than 85% but atleast 35 % by weight of
acrylonitrile units , except fibers qualifying under
subparagraphs 2 of paragraph j ( rubber) and the fiber
qualifying under paragraph g ( anidex)

The difference between acrylics and modacrylics is the


weight of the acrylonitrile units present .
Acrylic is 100% acrylonitrile .
Modacrylic is 60% vinyl chloride and 40% acrylonitrile .

Acrylonitrile may be made from acetylene or from


ethylene .
Etylene is treated with hypochlorous acid to form
chlorohydrin.
Chlorohydrin is reacted with sodium hydroxide to form
ethylene oxide .
Hydrocyanic acid is added to the ethylene oxide ,
producing cyanoalcohol , which is dehydrated to yield
acrylonitrile .
The acrylonitrile is then polymerised into poly
acrylonitrile resin , a long linear polymer .
The poly-acrylonitrile is dissolved in a suitable solvent ,
such as dimethyl- formamide , and extruded through a
spinneret.
After cogulation , the filaments are oriented and
stabilized by stretching .

Properties
Color , lustre , fineness and length can vary . Only staple
fibers are produced .
Microscopic features determined by method used for
spinning .
Tenacity - Stronger than wool and acetate but weaker
than most other fibers .
Varies from 2.0 to 3.6 g/d for acrylic . Looses approx 15
to 20 % strength when wet .
Modacrylic loosed approximately 12% strength when
wet .

Elongation and resilience Elongation and recovery of


the fibers is variable . At 2% elongation recovery is from
97% to 99% .
Have good resilience.
Density SEF modacrylic is heaviest of the fibres
.Acrylic fibers are similar in weight to nylon . They are
lighter than polyester and rayon but heavier than olefins
.
Moisture 1- 2% . More absorbent than olefin and
polyester but less absorbent than nylon .
Generate static electricity.

Thermal Properties decompose before they melt


although a fiber held close to a flame will shrink away
from it .
Acrylic fiber burns with a yellow flame .
They form hot gummy residue that drips away from the
burning material .
The materials are not self extinguished .
Modacrylics are difficult to ignite and they self
extinguish . The ash is hard black char.
Chemical Properties Weak alkalies do not affect
acrylics . Concentrated alkalies degrade alkalies but not
modacrylics.
Resistance to sunlight excellent .

Primary uses Apparel and home furnishings . Fibers


made from them are usually soft and light in weight.
Blends of acrylic and modacrylic are used in high pile
coat fabrics and carpeting . Socks , knit sweaters ,
sportwear fabrics , loungewear and sweat shirts .

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